Interaction of walsh orbitals in rotanes. Photoelectron spectroscopic investigation

Rolf Gleiter, Rudolf Haider, Jean‐Marie Conia, J. P. BARNIER, Armin de Meijere

Journal of the Chemical Society Chemical Communications · 1979 · 31 citations · 0 references

Concepts

Abstract

He I photoelectron spectroscopic investigations of bicyclopropylidene (4), [3]rotane (5), and [4]rotane (6) reveal considerably larger resonance integrals for (4) and (5) compared with values reported for bicyclopropyl and tricyclopropyl derivatives.