Publication | Closed Access
Structure and Photochemistry of C<sub>4</sub> as Studied by the Coulomb Explosion Imaging Method
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Citations
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1990
Year
EngineeringChemistrySpectra-structure CorrelationElectron MicroscopyElectron SpectroscopyStructure ElucidationPhotophysical PropertyCyclic C 4C 4Materials ScienceCluster SciencePhysicsPhotochemistryMechanistic PhotochemistryAtomic PhysicsPhysical ChemistryCoulomb Explosion ImagingQuantum ChemistryNatural SciencesSpectroscopyCluster Chemistry
Abstract The Coulomb Explosion Imaging (CEI) method was used to determine the structure and photochemistry of carbon clusters. The cyclic structure of C 4 was found using a combination of laser photodetachment techniques and the CEI method. The cyclic C 4 electron affinity was found to be 2.1 ± 0.1 eV, more than 1 eV lower than the electron affinity of the linear isomer.
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