Room‐Temperature Photoinduced Electron Transfer in a Prussian Blue Analogue under Hydrostatic Pressure

Abstract

In from the cold: The CoIIIFeII state of a CoFe Prussian blue analogue undergoes a CoIIIFeII→(CoIIFeIII)* electron transfer at room temperature when irradiated by visible light (532 nm; see scheme). This property was confirmed using energy-dispersive X-ray absorption spectroscopy at the Co and Fe K-edges of the piezo-induced CoIIIFeII state. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.