Reaction‐Temperature‐Dependent Supramolecular Isomerism of Coordination Networks Based on the Organometallic Building Block [Cu^I₂(μ₂‐BQ)(μ₂‐OAc)₂]

Abstract

Three supramolecular isomers, [Cu(μ4-BQ)(μ2-OAc)2]n (α phase), [Cu(μ3-BQ)(μ2-OAc)(μ3-OAc)]n (β phase), and [Cu(μ2-BQ)(μ3-OAc)2]n (γ phase), were crystallized by using the organometallic building block shown, which has two types of supramolecular synthon. Interestingly, these three supramolecular isomers were crystallized from the same solvent. BQ=benzoquinone. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z53463_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.