Synthesis of chiral Rh-bichep complexes, highly efficient catalysts for asymmetric hydrogenations

BINAP: an efficient chiral element for asymmetric catalysis

Ryōji Noyori, Hidemasa Takaya · Accounts of Chemical Research · 1990 · 1.3K citations

Natural Sciences, Biochemistry, Chemistry +8

Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids

Akira Miyashita, Arisa Yasuda, Hidemasa Takaya et al. · Journal of the American Chemical Society · 1980 · 999 citations

Natural Sciences, Chemistry, Catalysis +10

Axially Dissymmetric Bis(triaryl)phosphines in the Biphenyl series: Synthesis of (6,6′‐dimethylbiphenyl‐2,2′‐diyl)bis(diphenylphosphine) (‘BIPHEMP’) and analogues, and their use in Rh(I)‐catalyzed asymmetric isomerizations of <i>N,N</i>‐diethylnerylamine

Rudolf Schmid, Marco Cereghetti, Bernd Heiser et al. · Helvetica Chimica Acta · 1988 · 222 citations

Natural Sciences, Chemistry, Medicinal Chemistry +8

Mechanistic aspects of catalytic hydrogenation of ketones by rhodium(I)-peralkyldiphosphine complexes

Kazuhide Tani, Eiji Tanigawa, Yoshitaka Tatsuno et al. · Journal of Organometallic Chemistry · 1985 · 54 citations

Natural Sciences, Chemistry, Catalysis +11

Synthesis of Atropisomeric 2,2′-Bis(dicyclohexylphosphino)-6,6′-dimethyl-1,1′-biphenyl (BICHEP) and Its Use in Rh(I)-catalyzed Asymmetric Hydrogenation of Prochiral Olefins

Akira Miyashita, Haruhiko Karino, Jun-ichi Shimamura et al. · Chemistry Letters · 1989 · 40 citations

Natural Sciences, Chemistry, Catalysis +16