IEEE Sensors Journal · 2010 · 24 citations · 29 references
Natural SciencesChemistryPhysical ChemistrySpectroscopic AnalysisSpectroscopyAbsorption SpectroscopyOptical SpectroscopyRotational SpectroscopyTerahertz PhotonicsTerahertz SpectroscopyAtomic Transition FrequenciesChemical Species IdentificationGas MixturesMolecular Rotational ConstantsRotational Transition FrequenciesRotational Transition IntensitiesSpectroscopic Transition FrequenciesTerahertz Spectral Analysis
Different gases have been successfully fingerprinted on the basis of the distinct transition frequencies measured by frequency tuning a THz source developed by us. Our further analysis illustrates that one can reliably separate isotopologues by measuring and comparing their rotational constants. Based on our investigation of the N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O isotopologues, 29 rotational transition peaks were identified for the first time. For the gas mixtures, preliminary results indicate that one can identify the components of chemical species and the corresponding concentrations. Based on our spectroscopic results, the tunable THz source may offer a viable approach in the identifications and detections of chemical species.
29
The HITRAN 2004 molecular spectroscopic database
Laurence S. Rothman, D. Jacquemart, A. Barbé et al. · Journal of Quantitative Spectroscopy and Radiative Transfer · 2005 · 2.7K citations
THz time domain spectroscopy of biomolecular conformational modes
Andrea Markelz, Scott E. Whitmire, Jay Hillebrecht et al. · Physics in Medicine and Biology · 2002 · 302 citations