Publication | Closed Access
Characterisation of Fuel Cell Membranes as a Function of Drying by Means of Contact Angle Measurements
28
Citations
13
References
2004
Year
Drying ProcessMembrane StructureEngineeringFuel Cell MembranesMembrane CharacterizationContact Angle MeasurementsSoft MatterChemical EngineeringProton-exchange MembraneThermodynamicsInterfacial ChemistryMembrane DryingBiophysicsMaterials ScienceElectrochemical CellHeat TransferMembrane PermeationElectrochemistryMembrane FormationInterfacial Phenomena
Abstract In another paper in this volume, it is demonstrated that the electrochemical interface in MEAs, and thus the polarization performance of the resulting fuel cells, can be improved by optimising the hot‐pressing procedure in the MEA preparation. In particular, the extent of drying of the membrane during MEA preparation was shown to be critical. In the present investigation, the effect of the drying process, and thus water content, on the hydrophilicity, wetting, and surface energies of some fuel cell membranes is examined. Wetting and surface energies are well known to influence the bonding behaviour of materials. Conclusions about how membrane drying and changes in water content influence membrane bonding and the relative importance of these surface effects are drawn.
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