Phosphorus, sulfur, and silicon and the related elements · 1990 · 23 citations · 3 references
Natural SciencesChemistryCatalysisOrganic ChemistrySolid-state ChemistryHeterocyclic ChemistryHeterocyclic CompoundsSulfur ChemistrySulfur CompoundsSulfur DioxideSulfur OxidesSulfur Compound ChemistrySulfur Containing Organic CompoundsSulfur Dioxide ChemistrySulfur Heterocycles
Abstract The various types of gas/solid-reactions (addition, elimination, substitution, condensation, catalyzed cycloaddition) in different branches of sulfur chemistry (heterocycles, S-vinyl-compounds, thioethers, thiols, sulfur dioxide) are reviewed, new types and new synthetic applications added. The reactions run to completion in a short time. The advantages of avoiding solvents are discussed, some mechanistic hints obtained.
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