[(η‐<sup>5</sup>‐P<sub>5</sub>)Fe(η<sup>5</sup>‐C<sub>5</sub>Me<sub>5</sub>)], a Pentaphosphaferrocene Derivative

Otto J. Scherer, Thomas Brück

Angewandte Chemie International Edition in English · 1987 · 175 citations · 5 references

Concepts

Abstract

cyclo-P, like C5H, can function as a 6π-electron-donor in sandwich complexes: Reaction of [(η5-C5Me5)Fe(CO)2]2 and P4 affords 1, which has been characterized by NMR and mass spectroscopy. It is possible that cyclo-P is formed from P and P2.

References

5