Discussions of the Faraday Society · 1968 · 70 citations · 0 references
Natural SciencesChemistryAnalytical ChemistryElectrochemistrySpectroscopyCharge Transfer ReactionsElectrochemical KineticsElectrode KineticsElectrode MaterialsOxidation ReactionsOxidation-reduction ReactionsCharge Transfer KineticsElectrochemical OxidationElectrochemical Reaction MechanismsElectrode Reaction KineticsElectrode Reaction MechanismsKinetics Of Electrode ReactionsPlatinum ElectrodesTransparent Conducting Electrodes
The kinetics and mechanism for the oxidation of o-tolidine have been studied at both platinum and optically transparent electrodes. Spectral data show that the intermediate is a dimeric species. Evaluation of fast kinetic rates for homogeneous reactions following charge transfer is demonstrated using transparent electrode.