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Expedient and High-Yield Synthesis of Alkylphos-Phonyl Bichlorides Under Mild, Neutral Conditions: Reaction of Bis(Trimethylsilyl)Alkyl Phosphonates with Oxalyl Chloride/Dimethylformamide
34
Citations
8
References
1987
Year
High YieldsChemical EngineeringAlkyl PhosphonatesEngineeringDerivative (Chemistry)High-yield SynthesisAlkylphos-phonyl BichloridesOrganic ChemistryOrganometallic CatalysisNeutral ConditionsSynthetic ChemistryChemistryStereoselective SynthesisChemical DerivativeCorresponding Phosphonyl Dichlor-idesEnantioselective Synthesis
Abstract Structurally variant bis(trimethylsilyl)alkyl phosphonates were converted in high yields (80–88%, distilled) to the corresponding phosphonyl dichlor-ides upon reaction with (COCl)2/DMF.
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