Addition reactions of protonic reagents to optically active 2-phenyl-1,3,2-oxazaborolines

Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications

E. J. Corey, Raman K. Bakshi, Saizo Shibata · Journal of the American Chemical Society · 1987 · 1.4K citations

Natural Sciences, Chemistry, Biocatalysis +10

An asymmetric synthesis of MK-0417. Observations on oxazaborolidine-catalyzed reductions

Todd K. Jones, Julie J. Mohan, Lyndon C. Xavier et al. · The Journal of Organic Chemistry · 1991 · 151 citations

Natural Sciences, Chemistry, Biocatalysis +8

New bicyclic organylboronic esters derived from iminodiacetic acids

Teresa Mancilla, Rosalinda Contreras, Bernd Wrackmeyer · Journal of Organometallic Chemistry · 1986 · 141 citations

Natural Sciences, Chemistry, Medicinal Chemistry +14

Organoboranes. 53. A high-field variable-temperature proton and boron-11 NMR study of the effects of solvent and structure on reactivity in allylboration

Herbert C. Brown, Uday S. Racherla, Perry J. Pellechia · The Journal of Organic Chemistry · 1990 · 130 citations

Natural Sciences, Chemistry, Nuclear Chemistry +11

Chiral Oxazaborolidines as Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes

N. N. Joshi, Morris Srebnik, Herbert C. Brown · Tetrahedron Letters · 1989 · 110 citations

Natural Sciences, Chemistry, Catalysis +9