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Vibrational spectra of some gold(I), palladium(II), and platinum(II) complexes with trialkylphosphines and trialkylarsines
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1970
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Inorganic ChemistryMost CasesMolecular SpectroscopyVibrational SpectraEngineeringTriethylarsine Species Mx3l–SpectroscopyNatural SciencesInfrared SpectroscopyCoordination ComplexSpectra-structure CorrelationPhysical ChemistryChemistryTrimethylarsine Complexes AuxlSpectroscopic PropertyBiophysicsSpectroscopic MethodInorganic Compound
Infrared and in most cases, Raman spectra are reported for trimethylphosphine and trimethylarsine complexes AuXL, Au(PMe3)2+, MX3L–, M2X4L2, MX2L2(trans and cis), M2X2L42+, MXL3+, ML42+(M = Pd or Pt; X = Cl, Br or I), as well as for triethylphosphine and triethylarsine species MX3L–, M2X4L2 and MX2L2. Vibrational assignments are suggested where possible, and point of spectroscopic interest are noted. Frequency relationships between the systems are discussed.