An Efficient palladium-catalysed reaction of vinyl and aryl halides or triflates with terminal alkynes

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Natural Sciences, Chemistry, Catalysis +11

Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate

Yasuo Hatanaka, Tamejiro Hiyama · The Journal of Organic Chemistry · 1988 · 651 citations

Natural Sciences, Chemistry, Materials Science +14

The Substitution of Aryl Iodides with Cuprous Acetylides. A Synthesis of Tolanes and Heterocyclics¹

Robert D. Stephens, C. E. Castro · The Journal of Organic Chemistry · 1963 · 623 citations

Natural Sciences, Chemistry, Analytical Chemistry +7

Synthesis of aryl- and vinyl-substituted acetylene derivatives by the use of nickel and palladium complexes

L. Cassar · Journal of Organometallic Chemistry · 1975 · 577 citations

Natural Sciences, Chemistry, Organic Chemistry +8

Nickel- or palladium-catalyzed cross coupling. 31. Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism

Ei‐ichi Negishi, Tamotsu Takahashi, Shigeru Baba et al. · Journal of the American Chemical Society · 1987 · 298 citations

Natural Sciences, Chemistry, Catalysis +13