C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

Jyh‐Herng Ruei, Venukumar Patteti, Arun B. Ingle, Kwok‐Kong Tony Mong

Chemical Communications · 2014 · 58 citations · 43 references

Concepts

Abstract

We reported a remote control glycosylation method using the picoloyl protecting group for 2-deoxy-β-glycosidic bond formation. The method is applicable to various 2-deoxythioglycosyl donors and the utility is illustrated by the synthesis of a deoxytrisaccharide component of landomycins.

References

43