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Record Charge Carrier Mobility in a Room-Temperature Discotic Liquid-Crystalline Derivative of Hexabenzocoronene
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1999
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Materials ScienceOrganic Charge-transfer CompoundElectronic DevicesEngineeringSemiconducting PolymerHexaalkyl-substituted Hexabenzocoronene DerivativesNanoelectronicsHigh MobilityDiscotic MaterialsApplied PhysicsCondensed Matter PhysicsOrganic SemiconductorCharge SeparationChemistryCharge Carrier TransportCharge TransportFunctional MaterialsElectrical Insulation
The largest charge mobility yet for discotic materials has been achieved with a series of hexaalkyl-substituted hexabenzocoronene derivatives (see Figure). When the mesogenic alkyl groups are coupled to the aromatic core via paraphenylene moieties both the high mobility and liquid-crystallinity are retained even at room temperature, making the materials particularly attractive candidates for the conducting layer in electronic devices.