Publication | Closed Access
Porous Capsules {(M)M<sub>5</sub>}<sub>12</sub>Fe<sup>III</sup><sub>30</sub> (M=Mo<sup>VI</sup>, W<sup>VI</sup>): Sphere Surface Supramolecular Chemistry with 20 Ammonium Ions, Related Solution Properties, and Tuning of Magnetic Exchange Interactions
90
Citations
40
References
2009
Year
Inorganic ChemistryChemical EngineeringHydrogen-bonding OptionsEngineeringNanoporous MaterialAmmonium CationsMolecule-based MagnetSupramolecular AssemblyChemistryPorous CapsulesSupramolecular ChemistryAmmonium IonsFunctional MaterialsFunctionalized Capsule SurfaceMagnetic Exchange Interactions
A manifold of hydrogen-bonding options on a highly active, functionalized capsule surface exhibiting 20 crown ether type pores allows the fixation and recognition of 20 ammonium cations (see picture; W green, Fe orange, O red, N blue, H light gray), which are partially released in solution, thereby leading to related equilibria.
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