Vibrational excitation of<i>cis-</i>and<i>trans-</i>1, 2-difluoroethenes by electron impact: effect of dipole moment on the threshold peaks

Abstract

Vibrational excitation near threshold was measured in cis- and trans-difluoroethene with the aim of assessing the role of the dipole moment in threshold peaks. Threshold peaks were found in both the isomer with and the isomer without a permanent dipole moment, but only for IR-active vibrations. A comparison with cross sections calculated with the Born approximation revealed that a `nontrivial' contribution to the threshold peaks, that is, one which cannot be explained by direct dipole excitation, is found only for the isomer with a permanent dipole moment (cis).