Sc₃N@C₈₀‐Ferrocene Electron‐Donor/Acceptor Conjugates as Promising Materials for Photovoltaic Applications

Abstract

Intriguing materials for photovoltaics: The first trimetallic nitride endohedral metallofullerene covalently connected to a donor group is efficiently synthesized in a 1,3-dipolar cycloaddition reaction. Exclusive formation of the [5,6]-regioisomer in the isolated N-methyl-2-ferrocenyl-Ih-Sc3[email protected]80-fulleropyrrolidine is confirmed by NMR spectroscopy and electrochemistry (see picture). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z800473_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.