Angewandte Chemie International Edition · 2006 · 142 citations · 34 references
Natural SciencesChemical EngineeringChemistryCatalysisInorganic ChemistryOrganic ChemistryCatalyst DesignCatalyst SynthesisCatalytic MaterialsSupported CatalystsIonic Liquid CatalysisOrganic Compound ReactionsOrganic Oxidation ReactionsSilica SupportsWater-mediated Catalysis
Several carbon–carbon bond-forming reactions are catalyzed by a silica-supported scandium triflate catalyst combined with an ionic liquid. The combination of these two components creates a hydrophobic reaction environment in water (see scheme; blue: water, yellow: substrate, orange: ionic liquid).
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Catalytic reactions in ionic liquids.
Roger A. Sheldon · Chemical Communications · 2001 · 2.6K citations