Concepedia

Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction

Tomoshige Kobayashi, Sayuri Kobayashi

Molecules · 2000 · 10 citations · 7 references

DOIFull text

Open access

Concepts

Abstract

An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described.

References

7

Synthesis and Reactions of Vinylene Carbonate

Melvin S. Newman, Roger W. Addor · Journal of the American Chemical Society · 1955 · 122 citations

, , +4

VINYLENE CARBONATE

Melvin S. Newman, Roger W. Addor · Journal of the American Chemical Society · 1953 · 75 citations

, , +5

Transition Metal Mediated <i>Exo </i>Selective Diels−Alder Reactions:  Preparation of 2-Cobalt-Substituted 1,3-Dienes Containing <i>C</i><sub>2</sub> Symmetric 2,3-Dibenzobicyclo[2.2.2]octanedione Dioxime Equatorial Ligands and Their Use in Thermal and Lewis Acid Catalyzed 4 + 2 Cycloadditions

Marcus W. Wright, Mark E. Welker · The Journal of Organic Chemistry · 1996 · 59 citations

, , +14

Molecular Tweezers as Synthetic Receptors: Molecular Recognition of Electron-Deficient Aromatic Substrates by Chemically Bonded Stationary Phases

Markus Kamieth, Ulrich Burkert, Perry S. Corbin et al. · European Journal of Organic Chemistry · 1999 · 46 citations

, , +14

The regiospecific synthesis of an anthraquinone based upon the elaboration of the adduct of 1-acetoxyisobenzofuran with p-benzoquinone monoacetal

RA Russell, DAC Evans, RV Warrener · Australian Journal of Chemistry · 1984 · 15 citations

, , +7