Publication | Closed Access
Manipulating Liquid‐Crystal Properties Using a pH Activated Hydrazone Switch
92
Citations
55
References
2013
Year
Crystal StructureCholesterol UnitsEngineeringBiochemistryCrystal MaterialLiquid‐crystal PropertiesNatural SciencesMolecular SwitchPhysical ChemistryHydrazone SwitchProtein Phase SeparationChemistryCrystal FormationCrystallographyCrystal Structure DesignBiophysics
The long-range organization of a liquid crystal can be controlled by using an additive that consists of cholesterol units attached to a hydrazone switch. The acid/base-induced rotary motion in the switch is transmitted to the self-assembled supramolecular host, wherein this information is propagated and amplified. This process alters the photophysical properties of the host, which results in the change of the readout color from purple to green. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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