Deconvolution in the Frequency Domain

Abstract

The Finite Impulse Response Operator (FIRO) method for improving the resolution of bands in a frequency-domain spectrum, developed recently by Jones and Shimokoshi (Applied Spectroscopy 37, 59 (1983)), is discussed in detail and its relationship to the analogous method of Kauppinen et al. (Applied Spectroscopy 35, 271 (1981), is shown. Under-, self-, and over-deconvolution are discussed for simulated and experimental spectra. Deconvolution of instrumentally broadened bands is discussed and implemented for the v 1 , Raman band of CC1 4 ; use of a Gauss-Lorentz lineshape gives the best results for this band. General guidelines for application of the FIRO method are also given.