Concepedia

Glycopolymers via catalytic chain transfer polymerisation (CCTP), Huisgens cycloaddition and thiol–ene double click reactions

Leena Nurmi, Josefina Lindqvist, Rajan K. Randev, Jay A. Syrett, David M. Haddleton

Chemical Communications · 2009 · 143 citations · 32 references

DOI

Concepts

Abstract

CCTP has been used to give alkyne-functional macromonomers which are subsequently functionalised with sugar azides and thiols, using both CuAAC and thiol-ene Michael addition reactions, to yield end-functionalised glycopolymers in a convenient manner.

References

32

A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes

Vsevolod V. Rostovtsev, Luke G. Green, Valery V. Fokin et al. · Angewandte Chemie International Edition · 2002 · 11.5K citations

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Peptidotriazoles on Solid Phase:  [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

Christian W. Tornøe, Caspar Christensen, Morten Meldal · The Journal of Organic Chemistry · 2002 · 8.5K citations

, , +12

Thiol–enes: Chemistry of the past with promise for the future

Charles E. Hoyle, Tai Yeon Lee, Todd M. Roper · Journal of Polymer Science Part A Polymer Chemistry · 2004 · 1.4K citations

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Michael addition reactions in macromolecular design for emerging technologies

Brian D. Mather, K. V. Viswanathan, Kevin M. Miller et al. · Progress in Polymer Science · 2006 · 1.1K citations

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Robust, Efficient, and Orthogonal Synthesis of Dendrimers via Thiol-ene “Click” Chemistry

Kato L. Killops, Luis M. Campos, Craig J. Hawker · Journal of the American Chemical Society · 2008 · 781 citations

, , +8