Concepedia

An Improved Procedure for Aromatic Cyanation

David M. Tschaen, Richard Desmond, Anthony O. King, M. C. Fortin, Brenda Pipik, Steven A. King, Thomas R. Verhoeven

Synthetic Communications · 1994 · 181 citations · 3 references

DOI

Concepts

Abstract

Abstract An effective method for conversion of aryl bromides to aryl cyanides is described. The procedure involves treatment of the aryl halide with zinc cyanide in the presence of a catalytic amount of palladium (0).

References

3

Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

Ei‐ichi Negishi, Nobuhisa Okukado, Anthony O. King et al. · Journal of the American Chemical Society · 1978 · 307 citations

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Alumina Assisted Aryl Cyanation

James R. Dalton, Steven L. Regen · The Journal of Organic Chemistry · 1979 · 83 citations

, , +6

Nucleophilic Displacement Catalyzed by Transition Metal. IX. [Pd2(dba)3]·CHCl3–DPPF Catalyzed Cyanation of Aryl Halides and Aryl Triflates

Kentaro Takagi, Ken Sasaki, Yasumasa Sakakibara · Bulletin of the Chemical Society of Japan · 1991 · 72 citations · Full text

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