Chemical Communications · 2013 · 50 citations · 35 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryOrganic ChemistryCoordination ChemistryLigand BindingMetal-ligand BondingPorous MaterialsTransition Metal ComplexesMetal-organic Framework AdsorptionMetal-organic FrameworksPorphyrin ComplexesSelectivity
A "pillar-free", highly porous metalloporphyrinic framework (UNLPF-1) exhibiting eclipsed porphyrin arrays has been constructed from an octacarboxylate ligand connected with paddlewheel secondary building units. UNLPF-1 possesses two types of open metal sites and exhibits an efficient selectivity toward capture of CO2 over N2.
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Crystal structure of an integral membrane light-harvesting complex from photosynthetic bacteria
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Assembly of porphyrin building blocks into network structures with large channels
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