Publication | Closed Access
Covalent Organic Frameworks with High Charge Carrier Mobility
805
Citations
39
References
2011
Year
Materials ScienceInorganic ChemistryOrganic Material ChemistryEngineeringOrganic ElectronicsMetal-organic FrameworksCovalent Bonded FrameworkCrystalline Porphyrin CofsPorphyrin UnitOrganic SemiconductorOrganic ChemistryCovalent Organic FrameworksChemistryCharge Carrier MobilityHybrid MaterialsFunctional MaterialsPolymer ChemistryHost-guest Chemistry
Two types (imine and boronate) of covalent organic frameworks (COFs) having a porphyrin unit have been synthesized. The two highly crystalline porphyrin COFs (COF-366 and COF-66) display excellent chemical and thermal stability and are permanently porous. Two-dimensional extended layered structures of the two COFs demonstrate very high charge carrier mobility values (8.1 cm2 V−1 s−1).
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