Separation and Determination of Sulfur Homocycles by High Pressure Liquid Chromatography—Detection of Novel Sulfur Rings

Ralf Steudel, Hans‐Joachim Mäusle, Doris Rosenbauer, H. J. Möckel, Torsten Freyholdt

Angewandte Chemie International Edition in English · 1981 · 56 citations · 8 references

Concepts

Abstract

Thirteen new sulfur rings can be isolated without decomposition by reverse phase HPLC and detected by UV spectroscopy. Melts of S 8 contain all S n rings with n = 6–26; the mixture obtained on reaction of SC1 2 or S 2 C1 2 with KI consists of S n rings with n = 6–21 or of even‐numbered rings with up to 22 members. The separation of S 8 and Se 8 was accomplished in the same way.

References

8