The Journal of Organic Chemistry · 2007 · 62 citations · 13 references
Natural SciencesChemistryCatalysisOrganic ChemistryCarbene ComplexesCatalyst SynthesisHeterocycle SynthesisHeterocyclic ChemistryHeterocyclic CompoundsOrganic SynthesisCatalysis By Carbene ComplexesConjugated DienesHeterocyclic Catalysts
This paper describes a diamination process using di-t-butyldiaziridinone as nitrogen source and N-heterocyclic carbene-Pd(0) complex as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities.
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Christopher J. O’Brien, Eric Assen B. Kantchev, Cory Valente et al. · Chemistry - A European Journal · 2006 · 822 citations