Concepedia

Activation and Reactivity of (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes in Cross-Coupling Reactions

Mihai S. Viciu, R.F. Germaneau, Oscar Navarro, Edwin D. Stevens, Steven P. Nolan

Organometallics · 2002 · 386 citations · 9 references

DOI

Concepts

Abstract

Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

References

9

Palladium‐Catalyzed Regioselective Mono‐ and Diarylation Reactions of 2‐Phenylphenols and Naphthols with Aryl Halides

Tetsuya Satoh, Yuichiro Kawamura, Masahiro Miura et al. · Angewandte Chemie International Edition in English · 1997 · 583 citations

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Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex

Blake C. Hamann, John F. Hartwig · Journal of the American Chemical Society · 1997 · 572 citations

, , +12

General and Efficient Catalytic Amination of Aryl Chlorides Using a Palladium/Bulky Nucleophilic Carbene System

Jinkun Huang, Gabriella A. Grasa, Steven P. Nolan · Organic Letters · 1999 · 241 citations

, , +11

A Highly Efficient Catalyst for the Telomerization of 1,3-Dienes with Alcohols: First Synthesis of a Monocarbenepalladium(0)-Olefin Complex

Ralf Jackstell, Mario Gómez Andreu, Anja C. Frisch et al. · Angewandte Chemie International Edition · 2002 · 176 citations · Full text

, , +6

Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes

Erwan Galardon, Shailesh Ramdeehul, John M. Brown et al. · Angewandte Chemie International Edition · 2002 · 169 citations

, , +16