A Magnetically Recyclable Nanocomposite Catalyst for Olefin Epoxidation

Mohammadreza Shokouhimehr, Yuanzhe Piao, Jaeyun Kim, Young Jin Jang, Taeghwan Hyeon

Angewandte Chemie International Edition · 2007 · 323 citations · 86 references

Concepts

Abstract

“Attractive” catalyst: Molybdenum oxide nanoparticles have been incorporated into a mesoporous silica shell and coated on silica-coated magnetite nanoparticles for use as a magnetically separable heterogeneous epoxidation catalyst. This catalyst, which has a low Mo loading of 1 mol %, can be recycled and reused six times in the epoxidation of cis-cyclooctene with no major loss of activity (see picture).

References

86