Angewandte Chemie International Edition · 2013 · 213 citations · 26 references
Natural SciencesChemistryMaterials ScienceMolecular PhysicsOrganic ChemistrySingle-molecule BiophysicsFluorescence SpectroscopyLuminescent MaterialsPhotochemistryPhotochromic MaterialsPhotosynthetic PigmentsSingle-molecule Fluorescence SpectroscopyChromophore FormationChromophore PhotochemistryChromophore PhotophysicsChromophore StructureMolecular ChromophoresMolecular Switching BehaviorOrganic Dye Photophysics
Asserting its independence: A single organic molecule containing pyrene and rhodamine B chromophores separated by a peptide spacer formed a mechanochromic material whose fluorescence could be switched from blue to bluish-green and reddish by grinding. Modulation of the overlapped packing pattern of the pyrene excimer for blue emission was crucial for the reversible tricolored switching observed.
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