Concepedia

Diastereoselective synthesis of trans-1,2-disubstituted cyclopropanols from homoallyl or bis-homoallyl esters via tandem intramolecular nucleophilic acyl substitution and intramolecular carbonyl addition reactions mediated by Ti(OPr-i)4 / 2 i-PrMgBr reagent

A. N. KASATKIN, Fumie Sato

Tetrahedron Letters · 1995 · 69 citations · 9 references

DOI

Concepts

References

9

Titanium(IV) Isopropoxide-Catalyzed Formation of 1-Substituted Cyclopropanols in the Reaction of Ethylmagnesium Bromide with Methyl Alkanecarboxylates

Oleg G. Kulinkovich, Sergei V. Sviridov, Dmitry A. Vasilevski · Synthesis · 1991 · 263 citations

, , +5

Metal Complexes of Small Cycloalkynes and Arynes

Martin A. Bennett, Heinz Schwemlein · Angewandte Chemie International Edition in English · 1989 · 169 citations

, , +14

Catalytic Diastereoselective Synthesis of Cis-1,2-Disubstituted Cyclopropanols from Esters Using a Vicinal Dicarbanion Equivalent

E. J. Corey, S. A. RAO, Mark C. Noe · Journal of the American Chemical Society · 1994 · 156 citations

, , +8

Generation and reactions of low-valent titanium alkoxide-acetylene complexes. A practical preparation of allyl alcohols

Kousuke Harada, Hirokazu Urabe, Fumie Sato · Tetrahedron Letters · 1995 · 142 citations

, , +7

New, Efficient Method for the Synthesis of Allyltitanium Compounds from Allyl Halides or Allyl Alcohol Derivatives via Oxidative Addition. A Highly Efficient and Practical Synthesis of Homoallyl Alcohols

A. N. KASATKIN, Takashi Nakagawa, Sentaro Okamoto et al. · Journal of the American Chemical Society · 1995 · 116 citations

, , +4