1,<i>n</i>‐Hydrogen‐Atom Transfer (HAT) Reactions in Which <i>n</i>≠5: An Updated Inventory

Abstract

Hydrogen-atom transfer (HAT) counts amongst the most widely investigated routes to carbon-centered radicals. Intramolecular processes involving 1,5-HAT are widespread to promote regioselective radical "CH activation". The aim of this review is to draw up a comprehensive inventory of the less commonly encountered 1,n-radical translocations (n≠5) with the aim to update this topic with the most recent relevant data.