Concepedia

Novel generation of an o-quinone methide from 2-(2′-cyclohexenyl)phenol by excited state intramolecular proton transfer and subsequent C–C fragmentation

Julio Delgado, Amparo Espinós, M. Consuelo Jiménez, Miguel A. Miranda

Chemical Communications · 2002 · 10 citations · 16 references

DOI

Concepts

Abstract

Formation of an o-quinone methide via C-C fragmentation of a zwitterion formed by intramolecular excited state proton transfer from an o-allylphenol derivative is reported for the first time.

References

16

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Quinone Methide Intermediates from the Photolysis of Hydroxybenzyl Alcohols in Aqueous Solution

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Alkylation of Nucleic Acids by a Model Quinone Methide

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1995 Merck Frosst Award Lecture Quinone methides: relevant intermediates in organic chemistry

Peter Wan, Beverly Barker, Li Diao et al. · Canadian Journal of Chemistry · 1996 · 133 citations · Full text

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Flash Photolytic Generation of <i>o</i><i>rtho</i>-Quinone Methide in Aqueous Solution and Study of Its Chemistry in that Medium

Y. Chiang, A. J. Kresge, Yuyang Zhu · Journal of the American Chemical Society · 2001 · 90 citations

, , +14