Can we aminate Grignard reagents under Barbier conditions?

Chiral Magnesium Bis(sulfonamide) Complexes as Catalysts for the Merged Enolization and Enantioselective Amination of <i>N</i>-Acyloxazolidinones. A Catalytic Approach to the Synthesis of Arylglycines

David A. Evans, Scott G. Nelson · Journal of the American Chemical Society · 1997 · 251 citations

Natural Sciences, Chemistry, Catalysis +10

Asymmetric electrophilic amination: synthesis of .alpha.-amino and .alpha.-hydrazino acids with high optical purity

Cesare Gennari, Lino Colombo, Giorgio Bertolini · Journal of the American Chemical Society · 1986 · 217 citations

Natural Sciences, Chemistry, Medicinal Chemistry +11

Catalytic Enantioselective Amination of Enolsilanes Using <i>C</i><i>₂</i>-Symmetric Copper(II) Complexes as Chiral Lewis Acids

David A. Evans, Douglas S. Johnson · Organic Letters · 1999 · 173 citations

Natural Sciences, Chemical Engineering, Chemistry +15

The Barbier Reaction - A One-Step Alternative for Syntheses via Organomagnesium Compounds

C. Blomberg, F. Hartog · Synthesis · 1977 · 146 citations

Natural Sciences, Chemistry, Inorganic Chemistry +8

Asymmetric synthesis of α-amino acids and α-N-hydroxyamino acids via electrophilic amination of bornanesultam-derived enolates with 1-chloro-1-nitrosocyclohexane.

Wolfgang Oppolzer, Osamu Tamura · Tetrahedron Letters · 1990 · 127 citations

Natural Sciences, Chemistry, Medicinal Chemistry +10