Concepedia

Photo-induced tautomerisation of methyltrioxorhenium(vii): the intermediate in olefin metathesis?

Leigh J. Morris, Anthony J. Downs, Tim M. Greene, G. Sean McGrady, Wolfgang A. Herrmann, Peter Sirsch, Odd Gropen, Wolfgang Scherer

Chemical Communications · 2000 · 18 citations · 9 references

DOI

Concepts

Abstract

Matrix-isolated [CH3ReO3] tautomerises to [H2CRe(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

References

9

Methyltrioxorhenium as Catalyst for Olefin Oxidation

Wolfgang A. Herrmann, Richard W. Fischer, Dieter W. Marz · Angewandte Chemie International Edition in English · 1991 · 417 citations

, , +15

Methyltrioxorhenium as Catalyst for Olefin Metathesis

Wolfgang A. Herrmann, Werner Wagner, Uwe N. Flessner et al. · Angewandte Chemie International Edition in English · 1991 · 183 citations

, , +17

Essays on organometallic chemistry, VII. Laboratory curiosities of yesterday, catalysts of tomorrow: organometallic oxides

Wolfgang A. Herrmann · Journal of Organometallic Chemistry · 1995 · 151 citations

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Multiple bonds between main-group elements and transition metals. Part 133. Methyltrioxorhenium as a catalyst of the Baeyer-Villiger oxidation

Wolfgang A. Herrmann, Richard W. Fischer, João D. G. Correia · Journal of Molecular Catalysis · 1994 · 119 citations

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Kinetics and Mechanism of the Epoxidation of Alkyl-Substituted Alkenes by Hydrogen Peroxide, Catalyzed by Methylrhenium Trioxide

Ahmad M. Al‐Ajlouni, James H. Espenson · The Journal of Organic Chemistry · 1996 · 119 citations

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