Journal of the Chemical Society A Inorganic Physical Theoretical · 1967 · 50 citations · 0 references
Natural SciencesBiochemistryChemistryAnalytical ChemistryElectrochemistryPhysical ChemistryChemical PotentialElectroanalytical ChemistryElectrochemical KineticsElectrode KineticsEnzyme KineticsPka DeterminationAcid-catalyzed HydrolysisHydrolysisHydrolysis ReactionsNeutral HydrolysisPh Dependence Of HydrolysisPolynuclear ComplexesStandard Chemical PotentialStandard Electrode Potentials
Equilibrium constants have been determined both by pH titration and spectrophotometric methods for the stepwise formation at 25° of Pd(OH)2(aq) from Pd2+(aq) and OH–(aq). A standard electrode potential has been measured for the reaction Pd = Pd2++ 2e–. Possible formation of polynuclear species is considered and discussed.