Helvetica Chimica Acta · 1981 · 68 citations · 12 references
PharmacyChemistryMedicinal ChemistryBioorganic ChemistryNatural Product BiosynthesisOrganic ChemistryDegradation ProductsMicrobial BiotransformationStructural ElucidationChemical DegradationChemical Degradation PathwaysSpectroscopic IdentificationStructural Elucidation Of Degradants
Structure Elucidation of Elaiophylin: Spectroscopy and Chemical Degradation The structure of the antibiotic elaiophylin (azalomycin B) was elucidated by extended spectroscopic investigations and chemical degradation. Elaiophylin ( 26 ) is a macrodiolide with a 16membered dilactone ring. The synthesis of 7‐acetoxy‐6‐ethyl‐3‐octanone ( 14 ), the acetyl derivative of an important degradation product, is described.
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Shigeo Nozoe, Koichi Hirai, Kyosuke Tsuda et al. · Tetrahedron Letters · 1965 · 78 citations
Eine neue Synthese von (±)‐Pyrenophorin
Hans Gerlach, Konrad Oertle, Adolf Thalmann · Helvetica Chimica Acta · 1977 · 63 citations