Journal of the Chemical Society A Inorganic Physical Theoretical · 1967 · 18 citations · 0 references
Natural SciencesChemistryInorganic ChemistrySpectroscopic AnalysisSpectroscopyCoordination ChemistryInfrared SpectroscopyInorganic MaterialsInorganic SpectroscopyMetal-ligand BondingTransition Metal ComplexesCarbonyl Oxygen CoordinationCovalent InteractionsInfrared Absorption SpectraInfrared SpectraInfrared Spectroscopy Of Carbonyl ComplexesMetal-ligand Bonding AnalysisSpectroscopy Of Transition Metal Complexes
The infrared spectra of the complexes AlCl3,HCO2Me, AlCl3,Ph2CO, AlCl3,PhCOCl, and the complex of AlCl3 and COCl2 have been examined over the range 4000–80 cm.–1. The spectra are interpreted on the basis of covalent 1 : 1 complexes co-ordinated via carbonyl oxygen to aluminium.