Concepedia

Rh(I)-Catalyzed Silylation of Aryl and Alkenyl Cyanides Involving the Cleavage of C−C and Si−Si Bonds

Mamoru Tobisu, Yusuke Kita, Naoto Chatani

Journal of the American Chemical Society · 2006 · 181 citations · 14 references

DOI

Concepts

Abstract

The Rh(I)-catalyzed silylation of nitriles with disilanes is described. The cleavage of inert carbon-cyano and silicon-silicon bonds occurs in this catalysis.

References

14

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