Concepedia

Gold-catalyzed synthesis of nitrogen-containing heterocycles from ε-N-protected propargylic esters

Jianfeng Huang, Xuan Huang, Bo Liu

Organic & Biomolecular Chemistry · 2010 · 16 citations · 36 references

DOI

Concepts

Abstract

A mild and efficient gold-catalyzed tandem cyclization to piperidinyl enol esters has been developed with facilely available epsilon-N-Boc-protected propargylic esters.

References

36

Cycloisomerization of 1,<i>n</i>‐Enynes: Challenging Metal‐Catalyzed Rearrangements and Mechanistic Insights

Véronique Michelet, Patrick Y. Toullec, Jean‐Pierre Genêt · Angewandte Chemie International Edition · 2008 · 984 citations

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Recent advances in syntheses of heterocycles and carbocycles via homogeneous gold catalysis. Part 1: Heteroatom addition and hydroarylation reactions of alkynes, allenes, and alkenes

Hong C. Shen · Tetrahedron · 2008 · 521 citations

, , +15

Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes

Rebecca Lyn LaLonde, Benjamin D. Sherry, Eun Joo Kang et al. · Journal of the American Chemical Society · 2007 · 462 citations

, , +9

Highly Active Au(I) Catalyst for the Intramolecular<i>e</i><i>xo</i>-Hydrofunctionalization of Allenes with Carbon, Nitrogen, and Oxygen Nucleophiles

Zhibin Zhang, Cong Liu, Robert E. Kinder et al. · Journal of the American Chemical Society · 2006 · 455 citations

, , +14

Efficient Synthesis of Cyclopentenones from Enynyl Acetates via Tandem Au(I)-Catalyzed 3,3-Rearrangement and the Nazarov Reaction

Liming Zhang, Shaozhong Wang · Journal of the American Chemical Society · 2006 · 367 citations

, , +5