Publication | Closed Access
Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes
458
Citations
18
References
2007
Year
Asymmetric CatalysisInorganic ChemistryChemical EngineeringVinyl PyrrolidinesEngineeringOrganic ChemistryOrganometallic CatalysisCatalysis−Bis-p-nitrobenzoate ComplexesChemistryEnantioselective Intramolecular HydroaminationEnantioselective SynthesisAsymmetric Intramolecular Hydroamination
The asymmetric intramolecular hydroamination of allenes catalyzed by phosphinegold(I)−bis-p-nitrobenzoate complexes is described. This reaction is applicable to the enantioselective formation of vinyl pyrrolidines and piperidines in 70−99% ee.
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