Journal of the American Chemical Society · 2007 · 458 citations · 18 references
Asymmetric CatalysisInorganic ChemistryChemical EngineeringVinyl PyrrolidinesEngineeringOrganic ChemistryOrganometallic CatalysisCatalysis−Bis-p-nitrobenzoate ComplexesChemistryEnantioselective Intramolecular HydroaminationEnantioselective SynthesisAsymmetric Intramolecular Hydroamination
The asymmetric intramolecular hydroamination of allenes catalyzed by phosphinegold(I)−bis-p-nitrobenzoate complexes is described. This reaction is applicable to the enantioselective formation of vinyl pyrrolidines and piperidines in 70−99% ee.
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Catalytic asymmetric synthesis
Choice Reviews Online · 2001 · 2.7K citations
Chemical Engineering, Catalytic Asymmetric Synthesis, Engineering +10
Gold(I)-Catalyzed Stereoselective Olefin Cyclopropanation
Magnus J. Johansson, David J. Gorin, Steven T. Staben et al. · Journal of the American Chemical Society · 2005 · 525 citations