Concepedia

A concise synthesis of (−)-centrolobine via a diastereoselective ring rearrangement metathesis–isomerisation sequence

Verena Böhrsch, Siegfried Blechert

Chemical Communications · 2006 · 76 citations · 51 references

DOI

Concepts

Abstract

A total synthesis of (-)-centrolobine (1) based on a diastereoselective ring rearrangement metathesis-double bond isomerisation sequence and a one-pot cross metathesis-hydrogenation procedure is described.

References

51

Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands

Matthias Scholl, Sheng Ding, Choon Woo Lee et al. · Organic Letters · 1999 · 3.4K citations

, , +15

Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts

Steven B. Garber, Jason S. Kingsbury, Brian L. Gray et al. · Journal of the American Chemical Society · 2000 · 2K citations

, , +17

Olefin metathesis

Robert H. Grubbs · Tetrahedron · 2004 · 1.2K citations

A Recyclable Ru-Based Metathesis Catalyst

Jason S. Kingsbury, Joseph P. A. Harrity, Peter J. Bonitatibus et al. · Journal of the American Chemical Society · 1999 · 938 citations

, , +16

Synthesis and metathesis reactions of a phosphine-free dihydroimidazole carbene ruthenium complex

Simon Gessler, Stefan Randl, Siegfried Blechert · Tetrahedron Letters · 2000 · 511 citations

, , +9