Dinuclear Dysprosium(III) Single‐Molecule Magnets with a Large Anisotropic Barrier

Abstract

Dysprosium-based single-molecule magnets: Single-molecule magnets (SMMs) of dinuclear dysprosium(III) having thermal and quantum tunneling regimes of magnetization relaxation have been synthesized. Remarkably large energy barriers up to 71 K are observed, in particular for the polymeric complex network, which has the largest energy gap for a lanthanide complex and one of the highest barriers reported for a SMM. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.