Chemical Communications · 2006 · 143 citations · 41 references
Inorganic ChemistryChemical EngineeringAlkane HydroxylationEngineeringCatalytic ApplicationEfficient Turnover CatalystHeterogeneous CatalysisCatalytic SynthesisCatalysisMolecular CatalysisChemistryCatalyst PreparationCatalytic ProcessSimple Ni
A simple Ni(II)(TPA) complex [TPA = tris(2-pyridylmethyl)amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO(+) (nickel-oxo) type active oxygen species is suggested.
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