Journal of the Chemical Society Faraday Transactions · 1993 · 10 citations · 16 references
Natural SciencesChemistryMaterials ScienceSpectroscopySurface ChemistrySurface ScienceAdsorption At InterfacesOptical SpectroscopyRaman SpectroscopySurface AdsorptionSurface PhysicsSurface SpectroscopyAdsorption On Oxide SurfacesAdsorption On OxidesCoherent Anti-stokes Raman SpectroscopyInterferenceMonolayer AdsorptionMonolayer FilmsPhenol RemovalRaman Scattering Of Surfaces
Adsorption of phenol on a well defined (0001) surface of ZnO has been investigated with coherent anti-Stokes Raman scattering spectroscopy (CARS) using planar optical waveguide geometry. Monolayer sensitivity was achieved by establishing an interference condition within the ZnO layer to minimize the CARS signal from the film. At relatively higher surface coverages both physisorbed and chemisorbed phenol were present on the surface; however, with continuous pumping of the vacuum chamber all the physisorbed species were removed from the surface. The chemisorbed species is retained as the phenoxide on ZnO (0001) surface.
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The vibrational spectrum and torsion of phenol
H. D. Bist, J. C. D. Brand, D.R. Williams · Journal of Molecular Spectroscopy · 1967 · 224 citations
Natural Sciences, Chemistry, Physics +12
The vibrational spectra of phenol and phenol-OD
J. C. Evans · Spectrochimica Acta · 1960 · 191 citations
Natural Sciences, Chemistry, Physics +12