En route to optically active ethynylglycine derivatives

A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)

E. J. Corey, P.L. Fuchs · Tetrahedron Letters · 1972 · 1.6K citations

Natural Sciences, Chemical Engineering, Chemistry +7

Methanolysis of Dimethyl (1-Diazo-2-oxopropyl) Phosphonate: Generation of Dimethyl (Diazomethyl) Phosphonate and Reaction with Carbonyl Compounds

Susumu Ohira · Synthetic Communications · 1989 · 699 citations

Natural Sciences, Chemistry, Organic Chemistry +1

Suicide substrates: mechanism-based enzyme inactivators

Christopher T. Walsh · Tetrahedron · 1982 · 443 citations

Life Sciences, Biochemistry, Molecular Biology +14

The synthesis and configurational stability of differentially protected .beta.-hydroxy-.alpha.-amino aldehydes

Philip Garner, Jung Min Park · The Journal of Organic Chemistry · 1987 · 404 citations

Natural Sciences, Biochemistry, Chemistry +10

Diazoethenes: their attempted synthesis from aldehydes and aromatic ketones by way of the Horner-Emmons modification of the Wittig reaction. A facile synthesis of alkynes

John Gilbert, Upali Weerasooriya · The Journal of Organic Chemistry · 1982 · 254 citations

Natural Sciences, Chemistry, Catalysis +7