Journal of the Chemical Society D Chemical Communications · 1971 · 10 citations · 0 references
Natural SciencesChemistryInorganic ChemistryPhysical ChemistrySupramolecular ChemistryChemical BondingCoordination ChemistrySolution ChemistrySolvation EffectsSolvation TheoryTransition Metal ComplexesBondingBonding In Coordination CompoundsComplexation ChemistryCoordination BondingDielectric ConstantElectronic Structure Of Metal ComplexesIntermolecular Metal-ligand InteractionsMetal Ligand Coordination
The different bonding modes exhibited by the co-ordinated thiocyanate ion when the complex trans-Co-(dmg)2(Py)(SCN) is dissolved in high or low dielectric constant solvents have been shown to be kinetically controlled, rather than thermodynamically controlled, as was previously proposed by other workers.