Spectrum of Andreev Bound States in a Molecule Embedded Inside a Microwave-Excited Superconducting Junction

Abstract

Nondissipative Josephson current through nanoscale superconducting constrictions is carried by spectroscopically sharp energy states, the so-called Andreev states. Although theoretically predicted almost 40 years ago, no direct spectroscopic evidence of these Andreev bound states exists to date. We propose a novel type of spectroscopy based on embedding a superconducting constriction, formed by a single-level molecule junction, in a microwave QED cavity environment. In the electron-dressed cavity spectrum we find a polariton excitation at twice the Andreev bound state energy, and a superconducting-phase-dependent ac Stark shift of the cavity frequency. Dispersive measurement of this frequency shift can be used for Andreev bound state spectroscopy.